Simple Synthesis of Au−Pd Alloy Nanowire Networks as Macroscopic, Flexible Electrocatalysts with Excellent Performance

Jin Wang, Peina Zhang, Yujiao Xiahou, Dayang Wang, Haibing Xia,* and Helmuth Möhwald

ACS Appl. Mater. Interfaces 2018, 10, 1, 602-613

Abstract

The present work introduces a new way to prepare Au−Pd alloy nanowire networks (NWNs) via deposition of Pd atoms onto Au nanowires in reaction media at room temperature without the aid of additional reducing agents. Thanks to their excellent colloidal stability in water as well as in ethanol, the resulting NWNs can be utilized to produce composite thin films with Nafion (perfluorinated sulfonic acid) with dimensions above dozens of square centimeters by means of solution casting on the glass substrate. Most importantly, these films can be easily transferred onto different solid substrates by lift-off technology. Moreover, the resulting Au−Pd alloy NWNs can also be easily and thoroughly loaded into macroscopic carbon fiber cloth (CFC). Both the Au−Pd alloy NWN/Nafion composite film and the Au−Pd alloy NWN-loaded CFC can be used as flexible electrodes for electrocatalysis of ethanol oxidation, with electrocatalytic performance at different distorted states superior by 2 orders of magnitude to those reported in the literature (e.g., commercial Pd/C catalysts and Pd-based nanostructured catalysts). This work opens new possibilities for the large-scale manufacturing of electrodes for fuel cells.